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专家名称: 刘小明
联系方式: xiaoming.liu@mail.zjxu.edu.cn  
浏览人次: 1555
发布日期: 2013-11-13 15:25:54

专家介绍

博士、教授、博导、钱江学者    

个人简介

1981年毕业于赣南师院(专)化学教育专业,19849月至19861月在南京大学学习仪器分析硕士学位课程 (导师:陈洪渊院士、方惠群教授)1995年赴英国诺丁汉大学进修,同年10月获英国政府的海外研究生奖学金计划(Overseas Research Students Awards Scheme,ORS)及英国爱丁堡大学化学系助教奖学金资助攻读博士学位 (导师:Yellowlees 教授)19997月获博士学位。

出国前在赣南师院(专)工作,历任分析化学助教、讲师、分析化学教研室主任、副系主任。博士毕业后在英国的利兹大学 (University of Leeds)、约翰-英内斯中心 (John Innes Centre) 和东英吉利大学 (University of East Anglia) 从事博士后研究至2005年。200511月至201010月到南昌大学任教授(享受赣江特聘教授待遇)。自201011月起到嘉兴学院任教授、生物与化学工程学院执行院长现为浙江省钱江高级人才特聘教授。

曾任南昌大学学术委员会委员、南昌大学高等研究院研究员、高等研究院院务委员会委员、高等研究院微纳米材料科学与技术重点实验室主任、南昌大学理学院学术委员会副主任、化学系教授委员会主任。是Chem. Commun., Inorg. Chem., DaltonTrans., Org. Biomol. Chem., Phys. Chem. Chem. Phys., J. Bio. Inorg. Chem.,Inorg. Chim.

Acta, Inorg. Chem. Commun., Polyhedron,《中国科学》(英文版)、《自然科学进展》(英文版)、《高等学校化学学报》等国际和国内学术刊物的审稿人。

多次应邀在国际和国内学术会议上报告研究成果。1998年以来,发表了50多篇被SCI收录的学术论文,所涵盖的学术期刊有Nature, Angew Chem. Int. Ed., Coord. Chem. Rev., J. Am. Chem. Soc., Eur. J.Chem., Chem. Commun., Electrochem. Commun.,

J. Polym. Sci. Part A: Polym. Chem., Inorg. Chem., Dalton Trans., Electrochim. Acta, , New J.Chem., Tetrahedron等国际学术期刊。

研究方向

1. 金属酶模拟研究

2. 微纳米催化材料研究

3. 新型金属有机化合物的生物活性研究

4. 电化学

研究课题

1. Hmd-氢化酶辅酶的单核铁活性中心的模拟研究(国家自然科学基金,No.: 20871064, 2009.01-2011.1235万,负责人)

2. 全铁氢化酶的仿生物模拟研究-新型氢气发生催化剂的合成和催化电极的构造(国家自然科学基金,No.: 205710382006.01-2008.12 25万,负责人)

3. 模拟氢化酶和光系统II放氧酶太阳能转换制氢的研究(国家科技部,973项目,No.: 2009CB220009, 2009.01-2013.12.,与大连理工大学王梅教授合作,20万,主要成员)

4. 含氧配位原子的全铁氢化酶模型化合物的合成研究(教育部留学回国人员基金,2008.11-2010.11.3.5万,负责人)

5. 功能化纳米硅胶固体萃取剂的制备与应用研究(江西省教育厅,重点项目,2007.01-2008.12 3.0万,负责人)

教学工作

1. 本科教学:无机化学、大学化学、化学前沿

2. 研究生教学:生物无机化学、无机化学前沿

研究成果(代表性研究论文、专利和获奖)

1. Zhiyin Xiao, Zhenhong Wei, LiLong, Yongli Wang, David J. Evans, Xiaoming Liu*, Diiron carbonylcomplexes possessing a

{Fe(II)Fe (II)} core:synthesis,  characterisation, andelectrochemical  investigation,DaltonTrans., 2011,  DOI:10.1039/C0DT01465F.

2. Ying Tang, Zhenhong Wei, WeiZhong, Xiaoming Liu*, Diiron complexes pendant with phenolic group(s) asmimics  of  the diiron  sub-unit  of [FeFe]-hydrogenase: synthesis,  characterisation, and  electrochemical investigation,  Eur. J. Inorg. Chem.,  2011, DOI: 10.1002/ejic.201001092.

3. CaixiaZhan, Xiufeng Wang, Zhenhong Wei, David J Evans, Xiang Ru, Xianghua Zeng, XiaomingLiu*, Synthesis and charact-erisation of polymeric materials  consisting of {Fe2(CO)5}-unitand their relevance to the diiron sub-unit of [FeFe]-hydrogenase,  Dalton Trans., 2010, 39,11255-11262. 4. Xiang Ru, Xianghua Zeng, Zhimei Li, David J. Evans, CaixiaZhan, Ying Tang, Lianjie Wang, Xiaoming Liu*, Bio-inspired polymer  functionalised with a diiron carbonyl modelcomplex and its assembly onto the surface of a gold  electrode via  “click” chemistry, J. Polym. Sci. Part A: Polym. Chem.,2010, 48, 4120-4128.

5. Xianghua Zeng, Zhimei Li, ZhiyinXiao, Yanwei Wang, Xiaoming Liu*, Using pendant ferrocenyl group(s) asan intramo-  lecular standard to probethe reduction of diiron hexacarbonyl model complexes for the sub-unit of[FeFe]-hydrogenase,  Eelctrochem.Commun., 2010, 12, 342–345.

6. Xianghua Zeng, Zhimei Li, XiaomingLiu*, Mechanistic investigations into electrocatalytic substitutionreactions of two diiron

hexacarbonyl complexes by triphenyl phosphineligand, Electrochim. Acta, 2010, 55, 2179-2185.

7. Zhiyin Xiao, Fenfen Xu, Li Long,Yinqiu Liu, Giuseppe Zampella*, Luca De Gioia, Xirui Zeng, Qiuyan Luo, XiaomingLiu*,

Influence of the basicity ofinternal bases in di-iron model complexes  on hydridesformation  and their transformationinto  diiron hexacarbonyl form,  J. Organomet. Chem.,2010,695,721-729.

8. YanweiWang, Zhimei Li, Xianghua Zeng, Xiufeng Wang, Caixia Zhan, Yinqiu Liu, XiruiZeng, Qiuyan Luo and Xiaoming Liu*, Synthesis and characterisation of three diiron tetracarbonyl complexesrelated to the diiron centre of [FeFe]-hydrogenase and  their protonating, electrochemical investigations, New J. Chem.,2009, 33, 1780-1789.

9. Zhimei Li, Xianghua Zeng, ZhigangNiu, Xiaoming Liu*, Electrocatalytic investigations of a tri-ironcluster towards  hydrogen  evolution and relevance to[FeFe]-hydrogenase, Electrochim. Acta, 2009, 54, 3638-3644.

10. Xiufeng Wang, Zhimei Li, XiruiZeng, Qiuyan Luo, David J. Evans, Christopher J. Pickett* and Xiaoming Liu*,The iron

centre of the cluster-free hydrogenase (Hmd):low-spin Fe(II) or low-spin Fe(0)? Chem. Commun., 2008,3555-3557.

11. Fenfen Xu, Cédric Tard, XiufengWang, Saad K. Ibrahim, David L. Hughes, Wei Zhong, Xirui Zeng, Qiuyan Luo, Xiaoming

Liu* andChristopher J. Pickett*, Controlling Carbon Monoxide Binding at Di-iron UnitsRelated to the Fe-only Hydrogenase Sub-site, Chem. Commun., 2008,606-608.

12. Wei Zhong, Giuseppe Zampella,Zhimei Li, Luca De Gioia, Yinqiu Liu, Xirui Zeng, Qiuyan Luo, Xiaoming Liu*,Synthesis,

characterisation of two hexa-ironclusters with {Fe2S2(CO)x} (x = 5 or 6)fragments and  investigation into theirinter-conversion, J. Organomet. Chem., 693, 2008, 3751-3759.

13. Carl Redshaw, Xiaoming Liu,Shuzong Zhan, David L. Hughes, Hugo Baillie-Johnson,  Mark R. J. Elsegood, and Sophie H.  Dale,Rhenium Calix[4]arenes: Precursors to Novel Imaging and Cancer Therapy Agents, Eur.J. Inorg. Chem., 2008, 2698-2712.

14. Saad K. Ibrahim, Xiaoming Liu,Ce′dric Tard and Christopher J. Pickett*, Electropolymeric materialsincorporating subsite

structures related to iron-onlyhydrogenase: active ester functionalised poly(pyrroles) for covalent binding of{2Fe3S}-carbonyl /cyanide assemblies Chem. Commun., 2007,1535-1537.

15. Cédric Tard, Xiaoming Liu,Saad K. Ibrahim, Maurizio Bruschi, Luca De Gioia, Sian Davies, Xin Yang,Lai-Sheng Wang  and Christopher J.Pickett, Synthesis of the H-Cluster Framework of Iron-Only Hydrogenase, Nature,2005, 433, 610-613.

16. Xiaoming Liu, Saad K. Ibrahim, Cédric Tard and Christopher J. Pickett, Iron-onlyHydrogenase: Synthesis,Structural  andReactivity Studies of Model Compounds, Coord. Chem. Revs., 2005,249, 1641-1652.

17. Cedric Tard, Xiaoming Liu,David L. Hughes and Christopher J. Pickett, A novel {FeI-FeII-FeII-FeI}iron thiolate  carbonyl  assembly which electrocatalyse hydrogen evolution, Chem. Commun.,2005, 133-135.

18. Xiaoming Liu, Judith A. McAllister, Marcelo P. de Miranda, Eric J. L. McInnes, ColinA. Kilner and Malcolm A. Halcrow ,

Reactions of Copper(II) Salts with3{5}-Tert-butylpyrazole. Double-Cubane Complexes  with Bound ExogenousAnions,  and a Novel  Pyrazole Coordination mode, Chem. Eur.J., 2004, 10,1827-1837.

19. Xiaoming Liu, Marcelo P. de Miranda, Eric J. L. McInnes, Colin Kilner and Malcolm A.Halcrow, Antisymmetric Exchange

in Two Tricopper(II) Complexes Containing a[Cu33-OMe)]5+ Core, Dalton Trans.,2004, 59-64.

20. Xiaoming Liu, Judith A. McAllister, Marcelo P. de Miranda, Benjamin J. Whitaker, ColinA. Kilner, Mark Thornton-Pett and Malcolm A. Halcrow, Supramolecular Templatingof the Double-Cubane [{Cu3(HpztBu)63-Cl)(μ3-OH)3}2Cu]Cl6(HpztBu=5-tert-Butylpyrazole), Angew. Chem. Int. Ed.,2002, 41(5),756-758.

21. Xiaoming Liu, Abbie C. McLaughlin, Marcelo P. de Miranda, Eric J. L. McInnes, Colin.A. Kilner and M. A. Halcrow,

A cyclic hexacopper(II) fluorocomplex that encapsulate two fluoride anion, Chem. Commun., 2002,2978-2979.

22. Xiaoming Liu, Colin A. Kilner, Malcolm A. Halcrow, 3{5}-tert-Butylpyrazole is aditopic receptor for zinc(II) halides, Chem. Commun., 2002,704-705.

23. Xiaoming Liu, Simon A. Barrett, Colin A. Kilner, Mark Thornton-Pett and Malcolm A.Halcrow,Syntheses of New Hydroxy-[3.3] Orthocyclophanes as Models for GalactoseOxidase Tyr-Cys Cofactor, Tetrahedron, 58, 2002, 603-611.

24. Xiaoming Liu, Li Mei Lindy Chia, Colin A. Kilner, Lesley J. Yellowlees, MarkThornton-Pett, Swiatoslaw Trofimenko and Malcolm A. Halcrow, An intrmolecularπ-π interaction  has no  effect on the lifetime  of an  aryl radical cation, Chem. Commun., 2000, 1947-1948.

25. 《生物无机化学导论》(科学出版社,2010年,第三版)(第8章:光合作用及其化学模拟)

26. “氢化酶模拟研究2008年江西省高校科技成果一等奖

社会兼职

大连理工大学精细化工国家重点实验室兼职教授、南昌大学兼职教授、南昌大学高等研究院兼职研究员

专业协会

英国皇家化学学会会员


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